Efect of masterbarch aditive over a biodegradable film from thermoplastic starch and polylactic acid
Abstract
Due to the current requirements in clean plastic materials, the project was conducted to study the effect of a masterbatch additive on mechanical properties (stress analysis), barrier (desiccant method), optical (CIELab and CIECh scale) of a polymer composed by cassava starch, polylactic acid (PLA) and grey masterbatch (MBG) and by using the blown film extrusion technology polymer. It was established that the films has a permeability to water vapor on the 90th day of monitoring (5,75E-14 g/m*s*Pa), in the case of the oxygen permeability, the lower value occurred on day 30 (9,57503E19 mol/m*s*Pa), the water absorption and the solubility percentage decrease throughout changing to 97,9 % (day 8) a 86,3% (day 90) y 25,41% (day 8) a 19,61% (day 90), respectively. In relation whit the tensile modulus there wasn’t significant difference during the evaluation time, a decrease occurs in Young modulus (235,50 to 173,10 MPa) and the maximum elongation at break point (2,64 to 11,34 %). Regarding color, samples presented a luminosity value over 50, that is, neutrality in color; in the same manner in relation to Chroma (or saturation) (average value of 1,46) and a trend to neutral position on hue due to values close to 0. As supportDownloads
Languages:
es,en.References
JAKOVCEVIC, A., STEG, L., MAZZEO, N., CABALLERO, R., FRANCO, P., PUTRINO, N. and FAVARA, J. Charges for plastic bags: Motivational and behavioral effects. Journal of Environmental Psychology, 40, 2014, p. 372–380.
LÓPEZ, O., ZARITZKY, N., GROSSMANN, M. and GARCÍA, M. Acetylated and native corn starch blend films produced by blown extrusion. Journal of Food Engineering, 116(2), 2013, p. 286-297.
MENDOZA, R. y VELILLA, W. Metodología para la caracterización termo-mecánica de películas plásticas biodegradables. Prospect, 9(1), 2011, p. 6–51.
YANG, X., WISTRAND, A. and HAKKARAINEN, M. Improved dispersion of grafted starch granules leads to lower water resistance for starch-g-PLA/PLA composites. Composites Science and Technology, 86, 2013 p. 149-156.
REOLON, V., MARQUES, L., BORGES, J. and MENEGALLI, F.C. Water vapor barrier and mechanical properties of starch films containing stearic acid. Industrial Crops and Products, 41, 2013, p. 227-234.
SHI, R., ZHANG, Z., LIU, Q., HAN, Y., ZHANG, L., CHEN, D. and TIAN, W. Characterization of citric acid/glycerol co-plasticized thermoplastic starch prepared by melt blending. Carbohydrate Polymers, 69(4), 2007, p. 748-755.
OLIVATO, J.B., GROSSMANN, M., BILCK, A., YAMASHITA, F. and OLIVEIRA, L.M. Starch/polyester films: simultaneous optimisation of the properties for the production of biodegradable plastic bags. Polímeros, 23(1), 2013, p. 32-36.
GARCIA, P., AYUMI, M., YANASHITA, F., EIRAS, M.V., LAZARETTI, M. and MULLER, C.M. Improving action of citric acid as compatibiliser in starch/polyester blown films. Industrial Crops and Products, 52, 2014, p. 305-312.
AVÉRROUS, L. y HALLEY, P. Biocomposites based on plasticized starch. Biofuels, bioproducts and biorefining, 3, 2009, p. 329-343.
AYANA, B., SUIN, S. and KHATUA, B. Highly exfoliated eco-friendly thermoplastic starch (TPS)/poly (lactic acid) (PLA)/clay nanocomposites using unmodified nanoclay. Carbohydrate Polymers, 110, 2014, p. 430-439.
WOKADALA, O., EMMAMBUX, N. and SINHA, S. Inducing PLA/starch compatibility through butyl-etherification of waxy and high amylose starch. Carbohydrate Polymers, 112, 2014, p. 216-224.
DETYOTHIN, S. Production and characterization of thermoplastic cassava starch, functionalized poly (lactic acid), and their reactive compatibilized blends [Tesis Doctor en Filosofía]. Michigan (USA): Michigan State University, 2012.
HUNEAULT, M. and LI, H. Morphology and properties of compatibilized polylactide/thermoplastic starch blends. Polymer, 48, 2007, p. 270-280.
ZUO, Y.F, GU, J., QIAO, Z., TAN, H., CAO, J. and ZHANG, Y. Effects of dry method esterification of starch on the degradation characteristics of starch/polylactic acid composites. International Journal of Biological Macromolecules, 72, 2015, p. 391-402.
JOAQUI, D. Estudio de las propiedades ópticas y permeabilidad de vapor de agua en biofilms producidos a partir de almidón termoplástico de yuca (TPS), ácido poliláctico (PLA) y ε-policaprolactona (PCL) obtenidos por extrusión de tornillo simple [Tesis Ingeniero Agroindustrial]. Popayán (Colombia): Universidad del Cauca, Facultad de Ciencias Agrarias, 2012.
ALBÁN, P. Efecto del ácido cítrico en las propiedades de tensión y propiedades de barrera en películas elaboradas a base de almidón termoplástico de yuca [Tesis Ingeniero Agroindustrial]. Popayán (Colombia): Universidad del Cauca, Facultad de Ciencias Agrarias, 2014.
ARBOLEDA M.G. Obtención de una película flexible a partir de almidón termoplástico de yuca (Manihot esculenta Crantz) y ácido poliláctico [Tesis Ingeniero Agroindustrial]. Popayán (Colombia): Universidad del Cauca, Facultad de Ciencias Agrarias, 2014.
AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM). Standard Test Method for Tensile Properties of Thin Plastic Sheeting: ASTMD882–10. Philadelphia (USA): 2002, 9 p.
AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM). Standard Test Methods for Water Vapor Transmission of Materials: ASTM E96/E96M – 05. Philadelphia (USA): 2005, 11 p.
AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM). Standard Test Method for Determining Gas Permeability Characteristics of Plastic Film and Sheeting: ASTM D1434-82. Philadelphia (USA): 2009.
AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM). Standard Test Method for Water Absorption of Plastics: ASTM D570 – 98- 2010. Philadelphia (USA): 2010, 4 p.
AMERICAN SOCIETY FOR TESTING AND MATERIALS (ASTM). Standard Test Method for Transition Temperatures and Enthalpies of Fusion and Crystallization of Polymers by Differential Scanning Calorimetry: ASTM D 3418-08. Philadelphia (USA): 2008.
JOO, M., AURAS, R. and ALMENAR, E. Preparation and characterization of blends made of poly(l-lactic acid) and β -cyclodextrin: Improvement of the blend properties by using a Masterbatch. Carbohydrate Polymers, 86, 2011, p. 1022–1030.
MALÍ, S., GROSSMANN, M.V., GARCÍA, M., MARTINO, M. and ZARITZKY, N. Effects of controlled storage on thermal, mechanical and barrier properties of plasticized films from different starch sources. Journal of Food Engineering, 75, 2006, p. 453–460.
HERRERA, B., EIRAS, M.V. and YAMASHITA, F. Effect of the method of production of the blends on mechanical and structural properties of biodegradable starch films produced by blown extrusion. Carbohydrate Polymers, 86, 2011, p. 1344–1350.
JIMÉNEZ, A., FABRA, M.J., TALENS, P. and CHIRALT, A. Effect of re-crystallization on tensile, optical and water vapour barrier properties of corn starch films containing fatty acids. Food Hydrocolloids, 26, 2012, p. 302-310.
GARCÍA-TEJEDA, Y., LOPEZ, C., PEREZ, J.P., RENDÓN, R., JIMÉNEZ, A., FLORES, E., SOLORZA, J. and BASTIDA, C.A. Physicochemical and mechanical properties of extruded laminates from native and oxidized banana starch during storage. LWT-Food Science and Technology, 54, 2013, p. 447-455.
TEIXEIRA, E., CURVELO, A., CORREA, A.C., MARCONCINI, J.M., GLENN, G. and MATTOSO, L. Properties of thermoplastic starch from cassava bagasse and cassava starch and their blends with poly (lactic acid). Industrial Crops and Products, 37, 2012, p. 61– 68.
BYRNE, F., WARD, P.G., KENNEDY, J., IMAZ, N., HUGHES, D. and DOWLING, D. Study of the effect of masterbatch addition on the mechanical, thermal, optical and surface properties of poly (lactic acid). Journal of Polymers and the Environment, 17(1), 2009, p 28–33.
CASTAÑEDA, J.P. Estudio de la retrogradación en películas flexibles obtenidas a partir de mezclas de almidón nativo de Yuca, ácido poli-láctico (PLA) y policaprolactona (PCL) [Tesis Magíster en ingeniería, énfasis en ingeniería de materiales]. Cali (Colombia): Universidad del Valle, Facultad de Ingeniería, Escuela de Ingeniería de Materiales, 2012.
CRUSE, P. Introduction to Color Spaces. CIE Lab & Lch [online]. 2015. Citado en Julio 7 de 2015. Disponible desde internet: http://www.colourphil.co.uk/lab_lch_colour_space.shtml
Spanish
English


















.png)


